Chisato Ayazaki (綾崎 智里 Ayazaki Chisato) is the leader of The Valkyries
Chisato has waist-length brown hair and brown eyes.
Later, she is seen doing unusual training with Valkyrie Member 1, Valkyrie Member 2 and Valkyrie Member 3 where she is asked if the training was good enough to which she says she doesn't know after training they go to take a shower and she takes her tonfa's with and she says it's normal.
Chisato wields a tonfa, which is a stick with a perpendicular handle attached a third of the way down the length of the stick, and is about 15–20 inches (380–510 mm) long.
- The name Chisato means "wisdom, intellect" (智) (chi) and "village" (里) (sato).
- Chisato's surname Ayazaki means "design" (綾) (aya) and "cape, peninsula" (崎) (saki/zaki).